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Titre du document / Document title

Homogeneous ice nucleation in water and aqueous solutions

Auteur(s) / Author(s)

KOOP Thomas ;

Résumé / Abstract

This review provides an introduction to ice nucleation processes in supercooled water and aqueous solutions. Concepts for experimental techniques suitable to study homogeneous ice nucleation are addressed, in particular differential scanning calorimetry of inverse emulsions. Ice nucleation data from aqueous solutions have been analyzed using two approaches, and the interrelations between those are examined. It is argued that the ice nucleation process is driven entirely by thermodynamic quantities and how this can be understood in the context of three proposed theories for supercooled liquid water. Ice nucleation data for pure water droplets surrounded by a gas have been compiled and evaluated; within experimental uncertainty neither a volume dependent nucleation process nor a surface dependent nucleation process is convincingly supported by the analysis. Finally, open questions in the area of supercooled aqueous solutions and ice nucleation are discussed.

Revue / Journal Title

Zeitschrift für physikalische Chemie    ISSN  0044-3336 

Source / Source

2004, vol. 218, no11, pp. 1231-1258 [28 page(s) (article)]

Langue / Language

Revue : Multilingue

Editeur / Publisher

Oldenbourg, München, ALLEMAGNE  (1954-1990) (Revue)

Localisation / Location

INIST-CNRS, Cote INIST : 765 B, 35400012054442.0010

Nº notice refdoc (ud4) : 16233451

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