Titre du document / Document title

Correlation of the rates of solvolysis of 2-thiophenecarbonyl chloride

Auteur(s) / Author(s)

D'SOUZA Malcolm J. ; STANT-BOGGS Mary E. ; WHITE Robin ; KEVILL Dennis N. ;

Résumé / Abstract

The specific rates of solvolysis of 2-thiophenecarbonyl chloride are very well correlated by the extended Grunwald-Winstein equation over a wide range of solvents; contrary to previous claims of an S^N2 mechanism, the solvolyses are predominantly by an ionisation mechanism aided by nucleophilic solvation.

Revue / Journal Title

Journal of chemical research. Synopses    ISSN  0308-2342   CODEN JRPSDC 

Source / Source

2003, n^o12, pp. 775-777 [3 page(s) (article)]

Langue / Language

Anglais

Editeur / Publisher

Science Reviews, St. Albans, ROYAUME-UNI  (1977) (Revue)

Localisation / Location

INIST-CNRS, Cote INIST : 17523 B, 35400011692630.0100